Tetrabutylammonium Phosphate CAS 5574-97-0


Free Sample Tetrabutylammonium Phosphate CAS 5574-97-0
- Appearance:Powder
- Purity:99.8%
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Name: Tetrabutylammonium Phosphate
CAS: 5574-97-0
MOQ: 1KG
Directory Guidance on Tetrabutylammonium Phosphate
Chemical Structure
Basic Info:
Melting point | 151-154 °C(lit.) |
Boiling point | 81-82 °C |
density | 1.04 g/mL at 20 °C |
refractive index | n20/D 1.369 |
Fp | 43 °F |
storage temp. | 2-8°C |
Product Introduction:
Tetrabutylammonium Phosphate (TBAP for short) is an organic phosphate compound with the formula C16H36NO4P that consists of N(C4H9)4+ tetrabutylammonium ions and hydrogen phosphate ions (H2PO4-). TBAP typically appears as white crystallized solid or powder with an ideal melting temperature between 151-154degC; its moisture absorbing qualities require it to be stored under sealed conditions to preserve optimal storage conditions.
Tetrabutylammonium Phosphate plays an integral role in chemical analysis and chromatography techniques, especially high performance liquid chromatography (HPLC) techniques for the separation of substances such as phospholipids. Typically its concentration as an ion pair chromatography reagent is typically 0.5 mol/L aqueous solution which provides good stability and separation effects during analysis.
Tetrabutylammonium Phosphate plays an integral part of chemical synthesis. As both a catalyst and ligand for organic synthesis reactions, it plays an essential role. In solid-supported functionalization experiments using magnesium silicate as the substrate material, this substance helps increase its adsorption performance while simultaneously providing good thermal stability and low vapor pressure levels.
Though Tetrabutylammonium Phosphate has many applications in chemical and industrial fields, its safety characteristics must be carefully considered during its use. According to available information, it may cause irritation to eyes, skin, respiratory system and may be harmful when swallowed; accordingly, suitable protective equipment such as gloves and goggles must be worn during operation in a well-ventilated area for best results.
Nature and Specifications:
Item | Specification |
Product Name | Tetrabutylammonium Phosphate |
CAS No. | 5574-97-0 |
Appearance | Powder |
Shelf Life | 2 years |
Packing | As your requirements |
solubility | DMSO (Sparingly), Methanol (Soluble), Water (Soluble) |
form | Solution |
color | White to off-white |
Specific Gravity | 1.010 |
Odor | Amine like |
Product service:
- Certificate Of Analysis (COA)
- Material Safety Data Sheet (MSDS)
- Route of synthesis (ROS)
- Method of Aanlysis (MOA)
- Nuclear Magnetic Resonance (NMR)
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Tetrabutylammonium Phosphate is an important organophosphate compound that has been widely used in many fields due to its unique chemical properties and versatility. The chemical structure of Tetrabutylammonium Phosphate gives it good ion pair formation ability, thermal stability and low vapor pressure, which provide the basis for its application in different fields. The following will introduce its specific applications in various fields in detail.
The demand for Tetrabutylammonium Phosphate in the environmental protection field has increased significantly in recent years. In wastewater treatment, it can be used as a modifier for heavy metal ion adsorbents. This technology has been industrialized in many thermal power plants.
Tetrabutylammonium Phosphate has found great use as an electrolyte or additive in electrophoresis, electrodeposition and electrode reactions in electrochemistry. Due to its ionic liquid properties – low vapor pressure and thermal stability -, it can effectively adjust performance of electrochemical reactions; for instance in studies of electrochemical catalytic reduction of carbon dioxide it has proven efficient as an electrolyte; it can even improve overall efficiency under specific conditions! Furthermore it has also proven beneficial as part of batteries and capacitors in terms of improving their electrochemical performance and stability as an electrolyte component.
Tetrabutylammonium Phosphate (TBAP) is frequently utilized as a catalyst or ligand in chemical synthesis for organic reactions such as acylation, alkylation and esterification. Due to the structure of its tetrabutylammonium ion, this compound provides good phase transfer catalytic properties which facilitate reactions between organic and aqueous phases. When creating functionalized materials it can serve as an invaluable catalyst in synthesizing polymers or composite materials with specific properties – making its use invaluable in both materials science and organic synthesis fields alike.
Tetrabutylammonium Phosphate can also play an integral role in materials science and functionalization applications, particularly solid support materials. By combining it with materials such as magnesium silicate, functionalized materials with high adsorption capacity can be produced. These materials can then be used to remove heavy metal ions (such as lanthanum ions) from water with excellent efficiency and selectivity; or create imprinted polymers to selectively identify and separate specific ions.
Tetrabutylammonium Phosphate can also be utilized for other special applications beyond those mentioned here, including component of ionic liquids used as solvents, electrolytes and catalysts; preparation of standard stock solutions used to analyse food samples using high performance liquid chromatography (HPLC); among others. These uses extend its scope of usage further.
Compared with traditional quaternary ammonium salt compounds, the outstanding advantage of Tetrabutylammonium Phosphate lies in its unique ion synergistic effect. The hydrophobic environment provided by the tetrabutyl cation and the hydrophilicity of the hydrogen phosphate form a micro-reaction interface. This amphiphilic property makes it perform well in heterogeneous catalytic reactions. For example, in the transesterification reaction, the catalytic efficiency of TBPA is 2.3 times that of tetrabutylammonium bromide, and the reaction time is shortened by more than 50%. At the same time, the thermal stability of the hydrogen phosphate group (decomposition temperature> 250℃) is significantly better than that of chloride ions or nitrates, which is suitable for high temperature and high pressure reaction systems.
In terms of environmental friendliness, the bioaccumulation factor (BCF) of Tetrabutylammonium Phosphate is only 0.05, which is far below the EU REACH regulation limit (BCF < 1.0). The by-products produced in its production process are mainly water and a small amount of carbon dioxide, which complies with the twelve principles of green chemistry. Compared with fluorinated surfactants or heavy metal catalysts, the ecotoxicity of TBPA is reduced by more than 90%, which is particularly suitable for sensitive fields such as food packaging materials.
In terms of economic benefits, the large-scale production cost of this compound is about 25% lower than that of similar products. The industrial supply of raw materials tetrabutylammonium hydroxide and phosphoric acid is mature, and the synthesis process does not require precious metal catalysts. Taking lithium-ion battery electrolyte additives as an example, the cost of adding TBPA to each ton of electrolyte is only US$80-120, but it can increase the number of battery cycles by more than 500 times, with a significant return on investment.
Functional designability is another competitive advantage. By regulating the chain length of tetrabutyl or introducing substitution groups, a series of derivatives can be customized and developed. For example, the analogue obtained by replacing butyl with octyl has a 40% lower viscosity in ionic liquids and is more suitable for low-temperature application scenarios. This modular design capability gives it a unique position in the specialty chemicals market.
Finally, the synergistic effect of Tetrabutylammonium Phosphate with oxidants such as potassium persulfate has opened up a new technical path. In advanced oxidation processes (AOPs), TBPA increases the degradation efficiency of organic pollutants to more than 95% and increases the mineralization by 30% by stabilizing persulfate radicals. This combined technology has been successfully applied to pharmaceutical wastewater treatment, with COD removal rates stabilized at 98.5%-99.2%.
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